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金属有机框架（MOFs）本身的晶体结构决定了它多数以粉末形式存在，为了克服其在成型和回收上的不足，将纤维素与MOFs结合成为一种理想的选择。近年来，MOFs/纤维素复合材料因其可再生、高孔隙率、大比表面积以及易成形的特点备受关注。本文主要介绍了MOFs/纤维素复合材料的两种合成方法：原位合成和非原位合成，对该复合材料在降解有机污染物中的应用进行了综述，旨在为MOFs/纤维素复合材料的研究提供参考。目前，对于MOFs/纤维素复合材料的研究多集中在材料制备和性能表征方面，今后还应进一步探讨纤维素基体的性质对MOFs的负载以及复合材料性质的影响；同时，需要进一步探索无纤维素降解的预修饰方法以及MOFs的绿色合成路线，促进MOFs/纤维素复合材料的工业化生产和商业化使用。
Abstract：Metal-organic frameworks(MOFs) mainly exists in powder form due to its crystal structure. In order to overcome its shortcomings in forming and recycling, the combination of cellulose and MOFs has become an ideal choice. In recent years, MOFs/cellulose composites have attracted much attention due to their reproducibility, high porosity, large specific surface area and easy formability. In this paper, two synthesis methods of MOFs/cellulose composites are introduced: in-situ synthesis and non-in-situ synthesis, and the application of MOFs/cellulose composites in the degradation of organic pollutants is reviewed in order to provide some reference for the research of MOFs/cellulose composites. At present, the research on MOFs/cellulose composites mainly focuses on material preparation and performance characterization. The influence of the properties of cellulose matrix on the loading of MOFs and the properties of composites should be further investigated in the future research. Meanwhile, it is necessary to further explore the pre-modification method without cellulose degradation and the green synthesis route of MOFs to promote the industrial production and commercial use of MOFs/cellulose composites.
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基本信息:
DOI：
中图分类号:TB332;X505
引用信息:
[1]杨珊,乌日娜.MOFs/纤维素复合材料的制备及其对有机污染物的降解[J].天津造纸,2024,46(04):31-37.
基金信息: